Dichlorido-2κ2 Cl-{μ-6,6′-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato-1κ4 O 1,N,N′,O 1′:2κ2 O 1,O 1′}copper(II)zinc(II)
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چکیده
In the title compound, [CuZnCl(2)(C(19)H(20)N(2)O(4))], the Cu(II) ion exhibits a slightly distorted square-planar coordination geometry defined by two N atoms and two O atoms of the 6,6'-dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolate Schiff base ligand. The Zn(II) ion is also four-coordinated by the two phenolate O atoms of the Schiff base ligand and by two cis-coordinated chloride anions.
منابع مشابه
{6,6′-Dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-1κ4 O 1,O 1′,O 6,O 6′:2κ4 O 1,N,N′,O 1′}(ethanol-1κO)-μ-nitrato-1:2κ2 O:O′-dinitrato-1κ4 O,O′-samarium(III)zinc(II)
In the title heteronuclear Zn(II)-Sm(III) complex, [SmZn(C(18)H(18)N(2)O(4))(NO(3))(3)(CH(3)CH(2)OH)], with the hexa-dentate Schiff base compartmental ligand N,N'-bis-(3-methoxy-salicyl-idene)ethyl-enediamine (H(2)L), the Sm(III) and Zn(II) ions are triply bridged by two phenolate O atoms from the Schiff base ligand and one nitrate anion. The five-coordinate Zn(II) ion is in a square-pyramidal ...
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In the title compound, [Mn(2)Ni(C(17)H(14)Br(2)N(2)O(2))(2)(CN)(4)(H(2)O)(2)] or [{Mn(C(17)H(14)Br(2)N(2)O(2))(H(2)O)}(2)(μ-CN)(2){Ni(CN)(2)}], each Mn(III) atom is chelated by a Schiff base ligand via two N and two O atoms and is additionally coordinated by a water mol-ecule to give a slightly distorted octa-hedral geometry. Two such Mn(III) ions are linked by a square-planar Ni(CN)(4) unit, w...
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The title compound, [Fe(2)Ni(C(17)H(14)Br(2)N(2)O(2))(2)(CN)(4)(H(2)O)(2)] or [{Fe(C(17)H(14)Br(2)N(2)O(2))(H(2)O)}(2)(μ-CN)(2){Ni(CN)(2)}], is iso-structural with its Mn(III)-containing analogue. Each Fe(III) atom is chelated by a Schiff base ligand via two N and two O atoms and is additionally coordinated by a water mol-ecule, forming a slightly distorted octa-hedral geometry. The two Fe(III)...
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In the title heteronuclear complex, [CuSm(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)COCH(3))], the Cu(II) ion is five-coordinated by two O and two N atoms from the 6,6'-dimeth-oxy-2,2'-[propane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolate ligand (L) and by an O atom from the acetone mol-ecule in a square-pyramidal geometry. The Sm(III) ion is ten-coordinated by six O atoms from the three nitrate liga...
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In the title compound, [Cu(C(19)H(20)N(2)O(4))(H(2)O)]·C(2)H(3)N, the Cu(II) ion is coordinated by two N and two O atoms from the tetra-dentate Schiff base ligand, which contains a propyl-ene fragment disordered over two conformations in a 0.64 (1):0.36 (1) ratio, and one O atom from the water mol-ecule in a distorted square-pyramidal geometry. In the crystal structure, inter-molecular O-H⋯O hy...
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